[OopanpanoO]

Mission 1: Nice to meet you, I will beat you.
Who: Normal Ichigo vs. Renji
Requirements: Defeat Renji
Comments: You only get one life bar, Renji gets two.

Mission 2: The Blade and Me
Who: Normal Ichigo vs. Urahara
Requirements: Land final blow with Ichigo's getsuga tensho (square + x).

Mission 3: Ichigo Kurosaki vs. Gin Ishimaru
Who: Shikai Ichigo vs. Gin
Requirements: Defeat Gin
Comments: For some reason, I didn't get this mission until my second time through.

Mission 4: Cause For Confront
Who: Shikai Ichigo vs. Renji
Requirements: Land final blow in "Heat Transformation Mode" (Square + Triangle when life bar is flashing red).

Mission 5: Split Under The Red Stalk
Who: Kira vs. Hinamori
Requirements: Defeat Hinamori

Mission 6: Insanity & Genius
Who: Ishida (after removing sanrei gloves) vs. Mayuri
Requirements: Defeat Mayuri
Comments: Ishida's actually pretty strong in this battle. It's his character's "bankai" equivalent. Good old ranged attacks. Just keep in mind that each time you use one of the bow attacks (circle), some health is drained.

Mission 7: The Undead
Who: Shikai Ichigo vs. Kenpachi
Requirements: Defeat Kenpachi
Comments: This battle is much easier if you fill the Zangetsu support bar and activate it (hit R). Not sure if you need to be in that mode when you land your killing blow, but it should be full by the end of battle anyway.

Mission 8: The True Will
Who: Hitsugaya vs. Hinamori
Requirements: "Stun" Hinamori multiple times with your reiatsu by holding square.
Comments: Not sure of exact number of times I had to do this, if anyone knows, please tell me.

Mission 9: The Creeping Limit
Who: Hitsugaya vs. Gin
Requirements: Land killing blow with Hitsugaya's soten ni zase (Square + X or Circle)

Mission 10: Remanant
Who: Shikai Ichigo vs. Byakuya
Requirements: Defeat Byakuya
Comments: Don't remember this mission very well, but I don't believe there was anything special about it.

Mission 11: The Supernal Tag
Who: Yoruichi vs. Byakuya
Requirements: Survive for 1 minute.
Comments: Pretty easy if you just keep spamming Yoruichi's shunpo.

Mission 12: Blazing Souls
Who: Bankai Renji vs. Byakuya
Requirements: Defeat Byakuya
Comments: Fun battle, wish Renji's attacks with Zabimaru were faster though.

Mission 13: Only Mercifully
Who: Kenpachi vs. Komamura
Requirements: Defeat Komamura
Comments: This was my least favorite battle, Komamura's health regenerates (pretty quickly, too). I eventually defeated him by using a cheap combo of back+X then mashing circle.

Mission 14: Blackmoon Rizing
Who: Bankai Ichigo vs. Byakuya
Requirements: Defeat Byakuya
Comments: Bankai Ichigo is fun, thought he was underpowered at first, but I was wrong. (You can also let his hollow form take over if you hit square+circle)

Mission 15: Long Way to Say Goodbye
Who: Yoruichi vs. Soi Fon
Requirements: Defeat Soi Fon
Comments: You only get one life bar each. Also, you enter the battle with Yoruichi affected by homonka (hornet's crest). If you get hit with Soi Fon's special, it's an instant death.

Mission 16: Welcome to Purgatory
Who: Ukitake vs. Yamamoto
Requirements: Defeat Yamamoto... possibly with a special attack from Shunsui (hit R)
Comments: Not really sure if you HAVE to defeat him with an attack from Shunsui, but it seemed like Yamamoto wouldn't die right away from Ukitake's normal attacks.

Mission 17: Black and White
Who: Bankai Ichigo vs. Senkei Byakuya
Requirements: Defeat Byakuya
Comments: Both of you only have one life bar. Both start in "Heat Transformation Mode" where you deal more damage, but can't block. Just keep mashing buttons in this battle and he'll go down.

Mission 18: Behind Me, Behind You
Who: Matsumoto vs. Kira
Requirements: Defeat Kira
Comments: haha, Matsumoto's fun to play with. Her Up+Circle attack calls Haineko (Ash Cat) to the battle, which will stay on the screen for a while and attack Kira.

Mission 19: end of hypnosis
Who: Bankai Hitsugaya vs. Aizen
Requirements: Defeat Aizen
Comments: Hitsugaya is awesome, although I found that I couldn't do damage to Aizen except for using Hitsugaya's soul technique (Square + X or Circle)

Mission 20: The United Front
Who: Bankai Ichigo vs. Aizen
Requirements: Defeat Aizen


Source: Gamefaqs.

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